LIC LZC Niobium Tantalum Based Halide Solid Electrolyte For Solid State Battery Materials Research

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​​Model:LIC/LZC
 ​​​​​​Ionic Conductivity​​​​​:1.2–2.5 mS/cm ​
 Electrochemical Window​​​​:1.5–4.3 V ​​Density​​​​:2.8 g/cm³
 ​​​​​Moisture Sensitivity​:High
 ​​Processing​​​:Ball-mill for 10h (Zr-based) or sol-gel synthesis for Ta/Nb systems.
 ​Storage:Argon-filled glovebox (O₂/H₂O <0.1 ppm) for LIC; dry air (<30% RH) for LZC.
 Temperature​​:25°C
 MOQ: 10g
 Leading time: 5-7 working days

SKU: LIC/LZC Category:

LIC/LZC/niobium-based/tantalum-based Halide Solid Electrolytes For All-solid-state Battery Materials Research And Experiments

Material Overview​​

LIC (Li₃InCl₆), LZC (Li₂ZrCl₆), and Nb/Ta-based halide solid electrolytes represent cutting-edge solutions for next-generation all-solid-state batteries (ASSBs). These materials combine high ionic conductivity (>1 mS/cm), exceptional oxidation stability (>4 V vs. Li⁺/Li), and cost-effective processing, making them ideal for high-voltage cathode compatibility and lithium metal anode integration.

Key Material Systems​​

  1. ​​LIC (Li₃InCl₆)​​
    • ​​Conductivity​​: 1.2–2.5 mS/cm at 25°C
    • ​​Stability​​: Stable with NCM811 cathodes (4.3 V)
    • ​​Handling​​: Moisture-sensitive; requires glovebox processing
  2. ​​LZC (Li₂ZrCl₆)​​
    • ​​Conductivity​​: 0.4–1.67 mS/cm (doping-dependent)
    • ​​Cost​​: <$11.6/kg (lowest among halides)
    • ​​Air Stability​​: Tolerates 5% humidity
  3. ​​Nb/Ta-Based Halides​​
    • ​​Formula​​: Li₂₊ₓZr₁₋ₓMₓCl₆ (M = Nb, Ta; x ≤ 0.2)
    • ​​Conductivity​​: Up to 3.07 mS/cm (Ta/Nb co-doping)
    • ​​Voltage Stability​​: >4.6 V with LNMO cathodes

Performance Highlights​​

​​Property​​ ​​LIC​​ ​​LZC​​ ​​Nb/Ta Halides​​
​​Ionic Conductivity​​ 1.2–2.5 mS/cm 0.4–1.67 mS/cm 1.5–3.07 mS/cm
​​Electrochemical Window​​ 1.5–4.3 V 1.8–4.5 V 1.7–4.6 V
​​Density​​ 2.8 g/cm³ 2.77 g/cm³ 2.9–3.1 g/cm³
​​Moisture Sensitivity​​ High Moderate Low (fluorinated)

Research Applications​​

  • ​​Interface Engineering​​: Compatible with LiCoO₂, NCM811, and LNMO cathodes.
  • ​​Mechanical Properties​​: Soft enough for cold pressing (300MPa) to achieve 94% theoretical density.
  • ​​Doping Strategies​​:
    • ​​LZC​​: Dy³⁺/Ta⁵⁺ co-doping boosts conductivity to 1.67 mS/cm.
    • ​​LIC​​: Zr⁴⁺ substitution enhances moisture resistance.

Handling Guidelines​​

  1. ​​Storage​​: Argon-filled glovebox (O₂/H₂O <0.1 ppm) for LIC; dry air (<30% RH) for LZC.
  2. ​​Processing​​: Ball-mill for 10h (Zr-based) or sol-gel synthesis for Ta/Nb systems.
  3. ​​Safety​​: Decomposes in humid air (H₂S/HCl risk); use fume hoods for large-scale prep.

Note: Custom formulations (e.g., Li₂.₄Zr₀.₈Ta₀.₂Cl₆) available for high-voltage ASSB research.